电解质
离子液体
热稳定性
电极
锂(药物)
热分解
化学
电化学
离子键合
材料科学
差示扫描量热法
离子
无机化学
物理化学
有机化学
热力学
医学
物理
内分泌学
催化作用
作者
Candice Francis,Rosalie Louey,Karl Sammut,Adam S. Best
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2018-01-01
卷期号:165 (7): A1204-A1221
被引量:22
摘要
Ionic liquids are an alternative electrolyte for lithium-ion batteries which are expected to increase thermal stability of the device. The thermal stability of lithium bis(fluorosulfonyl)imide salt (LiFSI) in 1-methyl-3-propylpyrrolidinium bis(fluorosulfonyl)imide (P13FSI) ionic liquid electrolyte was investigated at elevated temperatures after cycling in contact with commercially available electrode materials. Six commercial electrodes were investigated; LiFePO4, Li1.2Ni0.15Co0.1Mn0.55O2, LiMn1.5Ni0.5O4, Li4Ti5O12, LiCoO2 and graphite. Differential scanning calorimetry was performed on electrode | electrolyte combinations in high pressure hermetically sealed crucibles from 25 to 600°C. Of the electrodes studied here, LiFePO4 showed the lowest heat release and Li4Ti5O12 showed the highest onset temperature under the conditions used. Additionally, the ionic liquid electrolyte showed superior thermal stability as compared to the conventional electrolyte when used with LiMn1.5Ni0.5O4 and Li4Ti5O12 electrodes. Incremental state of charge investigations with both LiFePO4 and Li4Ti5O12 half cells showed that thermal stability varies with state of charge of the electrode. The thermal stability advantage provided by P13FSI electrolyte with each electrode should be considered to determine if the benefits of higher decomposition temperatures are outweighed by the higher energy released during ionic liquid decomposition.
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