低密度聚乙烯
材料科学
相(物质)
电阻率和电导率
复合材料
渗流阈值
复合数
三元运算
乙烯-醋酸乙烯酯
聚合物
聚乙烯
炭黑
聚合物混合物
高分子化学
醋酸乙烯酯
共聚物
化学
有机化学
天然橡胶
电气工程
工程类
计算机科学
程序设计语言
作者
Tian Lan,Paul J. Brigandi,Xindi Yu,Michael Q. Tran,Jeffrey M. Cogen,Timothy J. Person,Jingxia Huang,Junsi Gu,Robin Ziebarth,Manish Talreja,Hari Katepalli
摘要
Abstract Medium to extra‐high voltage electrical cables typically comprise a semiconductive polymer composite layer to homogenize the electromagnetic field through the cables. The semiconductive layers usually contain a high content of carbon black (CB) for reduced electrical resistivity. In this study, we found that both the morphology and resistivity of a ternary polymer composite of CB/low density polyethylene (LDPE)/ethylene‐vinyl acetate (EVA) depend on CBs used and the order of addition. Three types of CB were investigated. CB‐A, which has the lowest surface energy and the most uniform surface energy profile, exhibits a strong affinity to LDPE and always segregates in the LDPE phase whether it is first added in the LDPE phase or the EVA phase. CB‐B and CB‐C, which have higher and less homogeneous surface energies, distribute differently with different orders of addition. We observe a significant reduction in the percolation threshold of CB‐A in the CB/LDPE/EVA composite, but not with CB‐B or CB‐C. Adding CB‐A in the LDPE phase first results in substantially lower resistivity than adding it in the EVA phase first, whereas adding CB‐B or CB‐C in the LDPE phase first results in higher resistivity than adding them in the EVA phase first.
科研通智能强力驱动
Strongly Powered by AbleSci AI