Triphenyltin(iv) adducts of diphosphoryl ligands: structural, electronic and energy aspects from X-ray crystallography and theoretical calculations

Triphenyltin(iv) adducts of diphosphoryl ligands, RR′P(O)–X–P(O)RR′, were introduced. The influence of the ligand structures on the crystal packing of the complexes and Sn-O interactions was discussed using geometrical and theoretical analysis.