Novel hydrostable Z‐scheme Ag/CsPbBr3/Bi2WO6 photocatalyst for effective degradation of Rhodamine B in aqueous solution

Abstract In this study, a hydrostable Z‐scheme Ag/CsPbBr 3 /Bi 2 WO 6 photocatalyst was designed and fabricated for the degradation of Rhodamine B (RhB). The structural instability of CsPbX 3 perovskites in water is one of the main obstacles that restrict their practical application in photocatalytic wastewater treatment. The photocatalyst was prepared in three steps: passivation of CsPbBr 3 nanocrystals (NCs) with 3‐mercaptopropionic acid (MPA), construction of a heterojunction between MPA‐passivated CsPbBr 3 NCs and Bi 2 WO 6 ultrathin nanosheets, and doping Ag nanoparticles as charge mediators in the heterojunction. The as‐obtained 5%Ag/20%CsPbBr 3 /Bi 2 WO 6 exhibits good stability and excellent photocatalytic activity. The degradation rate is 93.9% in 120 min, which is 4.41 times than that of Bi 2 WO 6 .