Bidirectional, Multilayer MXene/Polyimide Aerogels for Ultra‐Broadband Microwave Absorption

Abstract To obtain high‐performance electromagnetic microwave (EM) absorption materials with broad effective absorption bandwidth ( EAB ) and reduced thickness, designing structures has proved to be a promising way. Herein, ultra‐broadband multilayer bidirectional MXene/polyimide EM absorption aerogels containing multi‐structures on scales ranging from the micro‐ to the macroscale are produced with the aid of electric and temperature fields. On the microscale, under the action of electric force and temperature gradient, the ordered structures made of aligned Ti 3 C 2 T x MXene nanosheets and the microscale layered aerogel walls enable the bidirectional aerogel to achieve a wide EAB of 8.58 GHz at a thickness of 2.1 mm. This is ascribed to the numerous aligned nanosheets and layered aerogel walls perpendicular to the incident EMs, facilitating the conversion of electromagnetic energy into electrical energy. Furthermore, on the macroscale, the multilayer bidirectional aerogel with non‐gradient structures effectively resolves the conflict between impedance matching and energy loss, resulting in an ultrawide EAB of 9.41 GHz at a thickness of 3 mm. This innovative design of electric‐field‐assisted multilayer bidirectional aerogels with multiscale structural coupling may provide feasible and effective pathways for the development of advanced EM absorption materials.