化学
密度泛函理论
钙钛矿(结构)
氧化物
纳米技术
化学物理
计算化学
物理化学
结晶学
有机化学
材料科学
作者
Nazia Bibi,Muhammad Usman,Ruyhan
标识
DOI:10.1016/j.comptc.2024.114842
摘要
The physical properties of Na-based NaXO3 (X = Ge, Si) oxide-perovskite have been explored within the density functional theory (DFT)-based CASTEP code. Both compounds have a cubic shape with a space group Pm3m. The structural stability of these compounds has been assessed by employing the formation enthalpy computations. Regarding the electronic properties, it was found that NaGeO3 and NaSiO3 are p-type semiconducting materials with an indirect band gap. The total density of states (TDOS) and partial density of states (PDOS) confirm the amount of electron concentration in specific bands. Both materials absorb light more strongly, in the ultraviolet spectrum. Therefore, we believe these materials are good candidates for electronics and optoelectronic applications associated with collecting UV light. It is also found that the cubic forms of both compounds simplify their mechanical stability. These results not only enhance our understanding of NaXO3 materials but also open up new possibilities for the potential applications of these materials in various technological applications.
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