Engineering the Performance and Stability of Molybdenum Disulfide for Heavy Metal Removal

Molybdenum disulfide (MoS₂) has recently emerged as one of the most promising water nano-based adsorbent materials for heavy metal removal with the potential to provide an alternative to conventional water decontamination technologies. In this study, we demonstrate the trade-off between mercuric removal capacity and overall MoS₂ adsorbent stability, both driven by MoS₂ synthesis parameters. A bottom-up hydrothermal synthesis setup at various growth temperatures was employed to grow flower-like MoS₂ films onto planar alumina supports. A thorough material characterization suggests that an increase in growth temperature from 150 to 210 °C results in higher MoS₂ crystallinity. Interestingly, elevated growth temperatures resulted in poor mercuric removal (525 mg g^-1, K = 2.2 × 10^-3 h^-1), yet showed enhanced chemical stability (i.e., minimal molybdenum leaching during exposure to mercury). On the other hand, low growth temperatures produce amorphous supported MoS₂, exhibiting superb mercuric removal capabilities (5158 mg g^-1, K = 36.1 × 10^-3 h^-1) but displaying poor stability, resulting in substantial byproduct molybdate leaching. Mercuric removal by crystalline MoS₂ was accomplished by adsorption and electrostatic attraction-based removal mechanisms, whereas redox reactions and HgS crystallization-based removal mechanisms were more dominant when using amorphous MoS₂ for mercury removal. Overall, our study provides essential insights into the delicate balance between MoS₂ mercuric removal capabilities and MoS₂ degradation, both related to material synthesis growth conditions. Employment of nano-enabled water treatments in general, and MoS₂ for heavy metal removal in particular, requires us to better understand these important fundamental trade-off behaviors to achieve sustainable, effective, and responsible implementation of nanotechnologies in large scale systems.