Polar comonomers regulate and control the copolymerization of conjugated dienes and methoxystyrenes catalyzed by a CGC-type rare-earth metal catalyst

A new strategy utilizing the continuous coordination of heteroatoms of polar comonomers realized the regulation and controllability of the regioselectivity, M n , M w / M n and living nature of the copolymerization of polar olefins and conjugated dienes.