区域选择性
铑
电泳剂
烯丙基重排
催化作用
化学
组合化学
有机化学
作者
Jun Zheng,Bernhard Breit
标识
DOI:10.1002/anie.201813646
摘要
Abstract A rhodium/photoredox dual catalyzed regiodivergent α‐allylation of amines is described. As an atom‐economic and efficient method, alkynes and allenes are used as allylic electrophile surrogates in this novel protocol. With different reaction conditions, synthetically useful branched or linear homoallylic amines could be synthesized in good to excellent yields and regioselectivity. This straightforward strategy complements the traditional transition‐metal catalyzed allylation reactions.
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