催化作用
光热治疗
钯
碳纤维
辐照
材料科学
光化学
化学
化学工程
纳米技术
有机化学
复合材料
复合数
物理
工程类
核物理学
作者
Ziwen Liu,Lijuan Niu,Xupeng Zong,Li An,Dan Qu,Xiayan Wang,Zaicheng Sun
标识
DOI:10.1016/j.apcatb.2022.121439
摘要
The XC-72R supported Pd catalysts exhibit low-temperature catalytic activity for CO oxidation under light irradiation. The CO conversion can reach 100% with the light irradiation of 900 mW·cm-2 at a catalyst temperature of 100 °C. Pd/C catalysts with different Pd loading have similar performance enhancement under light irradiation. The activation energy of 1% Pd/C catalyst remains unchanged implying that CO oxidation belongs to photothermal catalytic oxidation. The enhanced performance could be ascribed to ultrahigh surface temperature (275 °C) induced by the light irradiation of 800 mW·cm-2 and detected by an IR camera. That is higher than the catalyst temperature (187 °C) measured by the thermocouple. Carbon generates a higher temperature than Pd NP, causing heat transfers from carbon to Pd NP. In contrast, Pd NP produces a higher temperature than Al2O3 for Pd/Al2O3 catalyst, and heat is transferred from Pd to Al2O3. These demonstrate that the enhanced performance contributes to the photothermal effect of carbon.
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