酞菁
化学
超分子化学
共价键
第2组金属有机化学
图层(电子)
金属
纳米技术
薄膜
金属有机化学
化学物理
分子
有机化学
催化作用
材料科学
作者
Mathieu Abel,Sylvain Clair,Oualid Ourdjini,M. Mossoyan,L. Porte
摘要
Supramolecular chemistry on a surface has produced a large variety of atomically controlled systems, but practical applications are seriously restricted by the use of weakly cohesive non-covalent bonds and by the confinement to a metal surface. Here we report on the formation of a well-ordered organometallic sheet consisting of two-dimensional polymeric phthalocyanine. Remarkably, the growth demonstrated on a metal surface can be extended onto a thin insulating film. We thus expect the intrinsic properties to be preserved, and the system should be easily transferable to real devices.
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