咔唑
化学
氰化
杂原子
三氟甲基化
过渡金属
组合化学
光化学
硝化作用
催化作用
有机化学
戒指(化学)
三氟甲基
烷基
作者
Ganapam Manohar Reddy,Naidu Sambasiva Rao,H. Maheswaran
标识
DOI:10.1002/ajoc.201600422
摘要
Abstract We report a concise, versatile, and practical method for ortho ‐C−H mononitration, monotrifluoromethylation and monocyanation of carbazole cores via a transition‐metal‐catalyzed reaction using an appropriate functional group source. The significant advantage of this transformation is the generation of highly site‐selective direct C1–heteroatom bonds that are geometrically difficult to access, in good to excellent yields.
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