Preparation of Anode Material for Lithium Battery from Activated Carbon

玉米芯 阳极 活性炭 碳纤维 法拉第效率 材料科学 体积热力学 锂(药物) 微型多孔材料 化学工程 电池(电) 锂离子电池 无定形碳 锂电池 比表面积 无定形固体 化学 吸附 原材料 复合材料 电极 离子 催化作用 有机化学 热力学 复合数 功率(物理) 物理化学 内分泌学 工程类 物理 医学 离子键合
作者
Sumrit Mopoung,Russamee Sitthikhankaew,Nantikan Mingmoon
出处
期刊:International Journal of Renewable Energy Development [Institute of Research and Community Services Diponegoro University (LPPM UNDIP)]
卷期号:10 (1): 91-96 被引量:5
标识
DOI:10.14710/ijred.2021.32997
摘要

This research study describes the preparation of corncob derivedactivated carbon to be used as anodematerial for the preparation of lithium ion battery.The corncob was activated at 900 °C for 3 hours with KOH used in a 1:3 weight ratio.The final product was analyzed for chemical, physical, and electrical properties.The results show that the activated carbon is amorphous and contains some graphitic carbon with interconnected nano-channels. Furthermore,carboxyl functional groups were detected on the surface of the activated carbon product.The observed morphological characteristics in terms of surface area, total pore volume, micropore volume, and average pore size are 1367.4501 m²/g, 0.478390 cm³/g, 0.270916 cm³/g, and 2.10872 nm, respectively.In addition, the product also exhibits low electrical resistance in the range 0.706W-1.071W.Finally, the specific discharge capacities at the 1st and the 2nd cycles of the corncob derived activated carbon anode material were 488.67mA h/g and 241.45 mA h/g, respectively with an average of about 225 Ah/kg between the 3rd cycle and the 5th cycle. The averagespecific charge capacities/specific discharge capacities at increasing charging rate of 0.2C, 0.5C, 1C, 2C, and 5C were approximated 190 mAh/g, 155 mAh/g, 135 mAh/g, 120 mAh/g, and 75 mAh/g, respectively, with 100%Coulombic efficiency in all 5 cycles.It was shown that the corncob derived activated carbon anode material has a relatively high rate capability, high reversibility, and rapid and stable capacity when compared to the general of biomass-derived carbon
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