光降解
材料科学
咪唑酯
半导体
纳米孔
纳米技术
沸石咪唑盐骨架
金属有机骨架
降级(电信)
荧光
光催化
光电子学
催化作用
吸附
化学工程
计算机科学
化学
光学
工程类
有机化学
物理
电信
生物化学
作者
Yuan Gao,Jiafei Wu,Jiaqi Wang,Yuxin Fan,Shiya Zhang,Wei Dai
标识
DOI:10.1021/acsami.9b23314
摘要
p-Type semiconductors enable new opportunities for the development of photocatalysts. Metal–organic frameworks (MOFs) could now be manufactured for a wide range of applications. The zeolitic imidazolate framework-8 (ZIF-8), in particular, shows important desirable properties like good stability and a high surface area. Considering the p-type semiconducting intrinsic catalytic performance of CuBi2O4 (CBO) and the unique porous nanostructure and stability of ZIF-8, in this paper, we innovatively propose and investigate a new p-type semiconductor@MOFs (CBO@ZIF-8) material. Moreover, we focus on its application as a novel dual-function platform for simultaneous detection and degradation. The experimental results reveal that the platform is well suited for absorption, degradation, and fluorescent detection of certain targets. Using the contaminant, antibiotic tetracycline, as an example, the platform confirms excellent fluorescence sensing performance and good photodegradation properties under visible light. These results could aid the future design and implementation of novel and more sophisticated multifunction p-type semiconductor@MOFs platforms. The presented strategy represents the early stages of a future, genuine, general, multifunction platform.
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