催化作用
双金属片
电催化剂
产量(工程)
过渡金属
材料科学
氧化物
普鲁士蓝
贵金属
金属
化学工程
氮气
电化学
无机化学
纳米技术
化学
电极
冶金
物理化学
有机化学
工程类
作者
Jia Wang,Haeseong Jang,Guangkai Li,Min Kim,Zexing Wu,Xien Liu,Jaephil Cho
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2020-01-01
卷期号:12 (3): 1478-1483
被引量:22
摘要
The development of highly efficient and inexpensive catalysts is still a tremendous challenge for the electrocatalytic nitrogen reduction reaction (NRR), which is a promising alternative to high-temperature and high-pressure industrial technologies for the synthesis of NH3. Herein, we report a facile and large scale strategy exploiting a porous non-precious bimetallic oxide of NiWO4 for the NRR under ambient conditions. Benefiting from the above-mentioned merits, the designed electrocatalyst achieved outstanding catalytic activities in both 0.1 M HCl (NH3 yield: (40.05 ± 1.45) μg h-1 mg-1cat., Faraday efficiency (FE): (19.32 ± 0.68)% at -0.3 V) and 0.1 Na2SO4 (NH3 yield: (23.14 ± 1.75) μg h-1 mg-1cat., Farady efficiency: (10.18 ± 0.62)% at -0.3 V), and these efficiencies are superior to most of the reported non-precious metals for the NRR. Furthermore, the prepared catalyst presented excellent stability in both acidic and neutral media for up to 20 h. This work opens a constructive avenue for optimizing the catalytic performance of metal oxides and other transition metal-based catalysts for NRRs.
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