Development of Thermochemical Heat Storage Based on CaO/CaCO3 Cycles: A Review

Due to the inconsistency and intermittence of solar energy, concentrated solar power (CSP) cannot stably transmit energy to the grid. Heat storage can maximize the availability of CSP plants. Especially, thermochemical heat storage (TCHS) based on CaO/CaCO3 cycles has broad application prospects due to many advantages, such as high heat storage density, high exothermic temperature, low energy loss, low material price, and good coupling with CSP plants. This paper provided a comprehensive outlook on the integrated system of CaO/CaCO3 heat storage, advanced reactor design, heat storage conditions, as well as the performance of CaO-based materials. The challenges and opportunities faced by current research were discussed, and suggestions for future research and development directions of CaO/CaCO3 heat storage were briefly put forward.