Ionomer content optimization in nickel-iron-based anodes with and without ceria for anion exchange membrane water electrolysis

Hydrogen production from anion exchange membrane water electrolysis (AEMWE) is an efficient cost-effective solution to renewable energy storage. Contrary to proton exchange membrane (PEM) electrolysis, AEMWE requires further optimization of its cell design, particularly for the kinetically unfavourable oxygen evolution anode half-cell reaction (OER). In this work we optimize the commercial Fumatech fumion ionomer content in AEMWE anodes using nickel (Ni) nanoparticles (NP) synthesized by chemical reduction. The optimal ionomer content is then applied to Ni-iron (Fe)-based NPs with and without ceria (CeO 2 ), all prepared using the same method. Scanning Electron Microscopy (SEM) of the resulting electrode surfaces, Particle-size Distribution (PSD) of the catalyst inks, and in-situ testing of the monometallic Ni NPs show that the best and most active catalytic layer is obtained using 15 wt% ionomer. AEMWE performance and short-term durability are evaluated in different concentrations of potassium hydroxide (KOH), where the Ni 90 Fe 10 is the best performing Ni-based electrode showing 1.72 V at 0.8 A cm −2 in 1 M KOH after IR-correction, and a degradation rate of 3.3 mV h −1 . The addition of ceria to the Ni-based catalysts shows more consistent mass transfer over time likely due to more efficient water transport and bubble release. • 15 wt% Fumion is required for high AEMWE performance of NiFe/CeO 2 nanoparticles. • Ni 90 Fe 10 shows a cell voltage of 1.72 V at 0.8 A cm −2 in 1 M KOH. • Ni 80 Fe 20 /10 wt% CeO 2 shows a cell voltage of 1.67 V at 0.4 A cm −2 in 0.1 M KOH. • Ni 90 Fe 10 shows the best stability of the Ni-based materials over 12 h at 0.5 A cm −2 • CeO 2 can help improve charge transfer as well as mass transfer over time.