Waste cooking oil transesterification by sulfonated polyphenylsulfone catalytic membrane: Characterization and biodiesel production yield

A route to waste cooking oil (WCO) transesterification to produce biodiesel using sulfonated polyphenylsulfone (S-PPS) and blends of polyphenylsulfone (PPS) and sulfonated polyphenylsulfone (PPS:S-PPS) as catalytic membranes was tested. Thin catalytic membranes from S-PPS and PPS:S-PPS presented a good balance between their ion exchange capacity (IEC), swelling degree, and weight loss after crosslinking. In particular, the crosslinked dense membrane with 56% sulfonation degree PPS:S-PPS 56 (MD 3 C) that presents IEC value 1.00 ± 0.02 meq H + /g and 328.37% swelling degree in methanol, shows the best balance. MD 3 C membrane transesterification reaction using WCO reached 86% biodiesel conversion with a WCO feedstock containing 0.24% water, 68 g/100 g of iodine value and 93% triglycerides. The use of S-PPS membrane acid-catalyzed biodiesel production from WCO is a promising and cleaner solution for preventing water and soil pollution with an added value. Further test should be performed to determine catalytic membrane stability, number of catalytic activity cycles and evaluate the sustainability of the PPS:S-PPS catalytic membranes for biodiesel production. • Waste cooking oils (WCO), 93% triglycerides, as feedstock for biodiesel production. • S-PPS acid catalytic membranes up to 54% sulfonation degree were prepared. • S-PSS catalytic membrane reaches 86% biodiesel conversion form WCO. • 300% S-PSS crosslinked membrane swelling facilitates WCO transesterification. • S-PPS catalytic membranes a solution for avoiding water and soil pollution by WCO.