A Long Life Moisture‐Enabled Electric Generator Based on Ionic Diode Rectification and Electrode Chemistry Regulation

Abstract Considerable efforts have recently been made to augment the power density of moisture‐enabled electric generators. However, due to the unsustainable ion/water molecule concentration gradients, the ion‐directed transport gradually diminishes, which largely affects the operating lifetime and energy efficiency of generators. This work introduces an electrode chemistry regulation strategy into the ionic diode‐type energy conversion structure, which demonstrates 1240 h power generation in ambient humidity. The electrode chemical regulation can be achieved by adding Cl − . The purpose is to destroy the passivation film on the electrode interface and provide a continuous path for ion‐electron coupling conduction. Moreover, this device simultaneously satisfies the requirements of fast trapping of moisture molecules, high rectification ratio transport of ions, and sustained ion‐to‐electron current conversion. A single device can deliver an open‐circuit voltage of about 1 V and a peak short‐circuit current density of 350 µA cm −2 . Finally, the first‐principle calculations are carried out to reveal the mechanism by which the electrode surface chemistry affects the power generation performance.