过电位
催化作用
共价键
化学
碱金属
纳米技术
阳极
电解
组合化学
化学工程
电极
材料科学
有机化学
电化学
物理化学
工程类
电解质
作者
Jiarui Yang,Chenxi Zhu,Wenhao Li,Xusheng Zheng,Dingsheng Wang
标识
DOI:10.1002/anie.202314382
摘要
Consuming one of the largest amount of electricity, the chlor-alkali industry supplies basic chemicals for society, which mainly consists of two reactions, hydrogen evolution (HER) and chlorine evolution reaction (CER). Till now, the state-of-the-art catalyst applied in this field is still the dimensional stable anode (DSA), which consumes a large amount of noble metal of Ru and Ir. It is thus necessary to develop new types of catalysts. In this study, an organocatalyst anchored on the single-atom support (SAS) is put forward. It exhibits high catalytic efficiency towards both HER and CER with an overpotential of 21 mV and 20 mV at 10 mA cm
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