Preparation study and simulation of high transmittance W–Sn–Zr Co-doped VO2 thin films prepared by sol-gel method for energy-saving smart windows

The thermochromic properties of vanadium dioxide (VO2) hold great promise for applications in smart glass windows. VO2 films exhibit a high phase transition temperature (Tc), low visible transmission (Tlum), and low solar modulating ability (ΔTsol), making them inadequate for the requirements of smart glass windows. While some improvement in VO2 film performance can be achieved through single-element doping, these limited enhancements still fall short of ideal results. Therefore, there is a pressing need for the improvement of VO2 films. In this study, we utilized the sol-gel method to prepare VO2 samples simultaneously doped with three elements: W, Sn, and Zr. Microscopic characterization confirmed the successful incorporation of these elements. Optical measurements, including ultraviolet–visible–near-infrared spectroscopy, were conducted to assess the optical properties of the films. Ultimately, outstanding Tlum (69%) and ΔTsol (14%) were achieved, along with an appropriate Tc (27.6 °C). Energy consumption simulations were performed using the EnergyPlus model with experimental data, revealing that compared to conventional glass, VO2 glass reduces total cooling energy consumption by 9.8%. In comparison to previous work, the multi-element-doped films push the performance limits of VO2 films, offering a viable approach for fabricating superior VO2 smart glass windows.