PDI‐Based Organic Small Molecule Regulated by Inter/Intramolecular Interactions for Efficient Solar Vapor Generation

Abstract Organic small molecules with processing feasibility, structural diversity, and fine‐tuned properties have the potential applications in solar vapor generation. However, the common defects of narrow solar absorption, low photothermal conversion efficiency, and photobleaching result in limited materials available and unsatisfactory evaporation performance. Herein, the perylene diimide (PDI) derivatives are exploited as stable sunlight absorbers for solar vapor generation. Particularly, the N , N' ‐bis(3,4,5‐trimethoxyphenyl)−3,4,9,10‐perylenetetracarboxylic diimide (PDI‐DTMA) is well‐designed with donor–acceptor–donor configuration based on plane rigid PDI core. The efficient photothermal conversion is enabled through strong intermolecular π–π stacking and intramolecular charge transfer, as revealed by experimental demonstration and theoretical calculation. The PDI‐DTMA with a narrow band gap of 1.17 eV exhibits expanded absorption spectrum and enhanced nonradiative transition capability. The 3D hybrid hydrogels (PPHs) combining PDI‐DTMA and polyvinyl alcohol are constructed. With the synergistic effect of solar‐to‐heat conversion, thermal localization management, water activation, and unobstructed water transmission of PPHs, the high water evaporation rates can reach 3.61–10.07 kg m −2 h −1 under one sun. The hydrogels also possess great potential in seawater desalination and sewage treatment. Overall, this work provides valuable insights into the design of photothermal organic small molecules and demonstrates their potentials in solar water evaporation.