立体中心
化学
催化作用
中心(范畴论)
硅
组合化学
立体化学
有机化学
对映选择合成
结晶学
出处
期刊:Chinese Journal of Organic Chemistry
[Shaghai Institute of Organic Chemistry]
日期:2023-01-01
卷期号:43 (10): 3388-3388
被引量:7
标识
DOI:10.6023/cjoc202306027
摘要
In the past two decades, organosilicon compounds bearing silicon-stereogenic centers have attracted extensive attention in the fields of organic synthesis, materials, and drug design.However, the expansion of organosilicon compounds in these fields has been greatly restricted by limited source of organosilicon compounds.Therefore, the development of highly efficient and selective asymmetric catalytic methods to obtain chiral organosilicon compounds with silicon-stereogenic centers is a challenging task that needs to be solved urgently.The latest research progress on new catalytic reaction systems for asymmetric synthesis of silicon-stereogenic center containing organosilanes since 2011 is mainly summarized.
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