Indolo[3,2‐b]indole‐based multi‐resonance emitters for efficient narrowband pure‐green organic light‐emitting diodes

Abstract Organic light‐emitting diodes (OLEDs) utilizing multi‐resonance (MR) emitters show great potential in ultrahigh‐definition display benefitting from superior merits of MR emitters such as high color purity and photoluminescence quantum yields. However, the scarcity of narrowband pure‐green MR emitters with novel backbones and facile synthesis has limited their further development. Herein, two novel pure‐green MR emitters (IDIDBN and t BuIDIDBN) are demonstrated via replacing the carbazole subunits in the bluish‐green BCzBN skeleton with new polycyclic aromatic hydrocarbon (PAH) units, 5‐phenyl‐5,10‐dihydroindolo[3,2‐ b ]indole (IDID) and 5‐(4‐( tert ‐butyl)phenyl)‐5,10‐dihydroindolo[3,2‐ b ]indole ( t BuIDID), to simultaneously enlarge the π‐conjugation and enhance the electron‐donating strength. Consequently, a successful red shift from aquamarine to pure‐green is realized for IDIDBN and t BuIDIDBN with photoluminescence maxima peaking at 529 and 532 nm, along with Commission Internationale de l'Eclairage (CIE) coordinates of (0.25, 0.71) and (0.28, 0.70). Furthermore, both emitters revealed narrowband emission with small full width at half‐maximum (FWHM) below 28 nm. Notably, the narrowband pure‐green emission was effectively preserved in corresponding devices, which afford elevated maximum external quantum efficiencies of 16.3% and 18.3% for IDIDBN and t BuIDIDBN.