Basics of Two‐dimensionalNMR

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标识
DOI:10.1002/9781119806721.ch1
摘要

Chapter 1 Basics of Two-dimensional NMR Book Editor(s):K. Ivanov, K. IvanovSearch for more papers by this authorP.K. Madhu, P.K. MadhuSearch for more papers by this authorG. Rajalakshmi, G. RajalakshmiSearch for more papers by this author First published: 14 April 2023 https://doi.org/10.1002/9781119806721.ch1 AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Abstract The introduction of pulse-Fourier transform NMR established a permanent link between the time-domain “physics” phenomena and the continuous-wave “chemistry” procedures. The principles of time-domain NMR are expressed most compactly in Liouville space , meaning the space of all orthogonal operators for the spin system. A general two-dimensional NMR pulse sequence is constructed by inserting an evolution interval and a mixing sequence into a 1D pulse sequence. In the majority of NMR experiments, the nuclear magnetization is detected by the Faraday induction of an electrical signal in a coil of wire close to the NMR sample, induced by precessing transverse magnetization. One of the most powerful and versatile principles of 2D NMR is that it allows the experimental determination of correlations in the NMR behavior of the nuclear spin system at two different points in time. Ernst , R.R. and Anderson , W.A. ( 1966 January). Application of fourier transform spectroscopy to magnetic resonance . Rev. Sci. Instrum . 37 ( 1 ): 93 – 102 . ISSN 0034-6748. Hahn , E.L. ( 1950 ). Spin Echoes . Phys. Rev . 80 : 580 – 594 . Hahn , E.L. and Maxwell , D.E. ( 1952 ). Spin echo measurements of nuclear spin coupling in molecules . Phys. Rev . 88 ( 5 ): 1070 – 1084 . Meiboom , S. and Gill , D. ( 1958 August). Modified spin-echo method for measuring nuclear relaxation times . Rev. Sci. Instrum . 29 ( 8 ): 688 – 691 . ISSN 0034-6748. 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