亲爱的研友该休息了!由于当前在线用户较少,发布求助请尽量完整地填写文献信息,科研通机器人24小时在线,伴您度过漫漫科研夜!身体可是革命的本钱,早点休息,好梦!

Basics of Two‐dimensionalNMR

脉冲序列 傅里叶变换 磁化 核磁共振波谱 物理 自由感应衰变 核磁共振 自旋(空气动力学) 磁化转移 自旋扩散 化学 耦合 序列(生物学) 核磁共振谱数据库 自旋回波 凝聚态物理 谱线 量子力学 磁场 医学 生物化学 铁磁性 磁共振成像 放射科 热力学
标识
DOI:10.1002/9781119806721.ch1
摘要

Chapter 1 Basics of Two-dimensional NMR Book Editor(s):K. Ivanov, K. IvanovSearch for more papers by this authorP.K. Madhu, P.K. MadhuSearch for more papers by this authorG. Rajalakshmi, G. RajalakshmiSearch for more papers by this author First published: 14 April 2023 https://doi.org/10.1002/9781119806721.ch1 AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Abstract The introduction of pulse-Fourier transform NMR established a permanent link between the time-domain “physics” phenomena and the continuous-wave “chemistry” procedures. The principles of time-domain NMR are expressed most compactly in Liouville space , meaning the space of all orthogonal operators for the spin system. A general two-dimensional NMR pulse sequence is constructed by inserting an evolution interval and a mixing sequence into a 1D pulse sequence. In the majority of NMR experiments, the nuclear magnetization is detected by the Faraday induction of an electrical signal in a coil of wire close to the NMR sample, induced by precessing transverse magnetization. One of the most powerful and versatile principles of 2D NMR is that it allows the experimental determination of correlations in the NMR behavior of the nuclear spin system at two different points in time. Ernst , R.R. and Anderson , W.A. ( 1966 January). Application of fourier transform spectroscopy to magnetic resonance . Rev. Sci. Instrum . 37 ( 1 ): 93 – 102 . ISSN 0034-6748. Hahn , E.L. ( 1950 ). Spin Echoes . Phys. Rev . 80 : 580 – 594 . Hahn , E.L. and Maxwell , D.E. ( 1952 ). Spin echo measurements of nuclear spin coupling in molecules . Phys. Rev . 88 ( 5 ): 1070 – 1084 . Meiboom , S. and Gill , D. ( 1958 August). Modified spin-echo method for measuring nuclear relaxation times . Rev. Sci. Instrum . 29 ( 8 ): 688 – 691 . ISSN 0034-6748. Hartmann , S.R. and Hahn , E.L. ( 1962 ). Nuclear double resonance in the rotating frame . Phys. Rev . 128 : 2042 – 2053 . Bloch , F. ( 1946 October). Nuclear Induction . Phys. Rev . 70 ( 7-8 ): 460 – 474 . Cooley , J.W. and Tukey , J.W. ( 1965 ). An algorithm for the machine calculation of complex Fourier series. Math. Comp . 19 ( 90 ): 297 – 301 . ISSN 0025-5718, 1088-6842. Atmanspacher, H. Remembering Hans Primas ( 1928 –2014). (2014 January). Mind Matter . Banwell , C.N. and Primas , H. ( 1963 April). On the analysis of high-resolution nuclear magnetic resonance spectra . Mol. Phys . 6 ( 3 ): 225 – 256 ISSN 0026-8976. Sørensen , O.W. , Eich , G.W. , Levitt , M.H. , Bodenhausen , G. and Ernst , R.R. ( 1984 ). Product operator formalism for the description of NMR pulse experiments. Prog. Nucl. Magn. Reson. Spectrosc . 16: 163–192. ISSN 0079-6565. Ernst , R.R. , Bodenhausen , G. and Wokaun , A. ( 1990 September). Principles of Nuclear Magnetic Resonance in One and Two Dimensions , volume 1. Clarendon Press, Oxford. Tjandra , N. and Bax , A. ( 1997 November). Direct Measurement of distances and angles in biomolecules by NMR in a dilute liquid crystalline medium. Science . Cavanagh , J. , Fairbrother , W.J. , Palmer III , A.G. , Rance , M. and Skelton , N.J. ( 2007 ). Protein NMR Spectroscopy. Principles and Practice , 2e . Amsterdam : Elsevier Academic Press . Jeener , J. ( 1982 January). Superoperators in Magnetic Resonance. In: Advances in Magnetic and Optical Resonance , (ed. Waugh, J.S.), volume 10, 1–51. Academic Press. Levitt , M.H. and Bengs , C. ( 2021 June). Hyperpolarization and the physical boundary of Liouville space . Magn. Reson . 2 ( 1 ): 395 – 407 . ISSN 2699-0016. Kuprov , I. ( 2016 September). Fokker-Planck formalism in magnetic resonance simulations. J. Magn. Reson . 270: 124–135. ISSN 1090-7807. Bengs , C. and Levitt , M.H. ( 2020 January). A master equation for spin systems far from equilibrium. J. Magn. Reson . 310: 106645. ISSN 1090-7807. Levitt , M.H. ( 2012 ). Singlet Nuclear Magnetic Resonance . Annu. Rev. Phys. Chem . 63 ( 1 ): 89 – 105 . Carravetta , M. and Levitt , M.H. ( 2004 May). Long-lived nuclear spin states in high-field solution NMR . J. Am. Chem. Soc ., 126 ( 20 ): 6228 – 6229 . ISSN 0002-7863. Maricq , M.M. and Waugh , J.S. ( 1979 April). NMR in rotating solids . J. Chem. Phys . 70 ( 7 ): 3300 – 3316 . ISSN 0021-9606. Hall , D.A. , Maus , D.C. , Gerfen , G.J. , Inati , S.J. , Becerra , L.R. , Dahlquist , F.W. and Griffin , R.G. ( 1997 May). Polarization-enhanced NMR spectroscopy of biomolecules in frozen solution . Science , 276 ( 5314 ): 930 – 932 . ISSN 0036-8075, 1095-9203. Ardenkjaer-Larsen , J.H. , Fridlund , B. , Gram , A. , Hansson , G. , Hansson , L. , Lerche , M.H. , Servin , R. , Thaning , M. and Golman , K. ( 2003 September). Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR . Proc. Natl. Acad. Sci. USA 100 ( 18 ): 10158 – 10163 . Navon , G. , Song , Y.Q. , Room , T. , Appelt , S.T.R.E. , Taylor , R.E. and Pines , A. Enhancement of solution NMR and MRI with laser-polarized xenon . Science 271 ( 5257 ): 1848 – 1851 . ISSN 0036-8075, 1095-9203. Icker , M. and Berger , S. ( 2012 ). Unexpected multiplet patterns induced by the Haupt-effect. J. Magn. Reson . 219 ( 0 ): 1 – 3 . ISSN 1090-7807. Dumez , J.N. , Håkansson , P. , Mamone , S. , Meier , B. , Stevanato , G. , Hill-Cousins , J.T. , Roy , S.S. , Brown , R.C. , Pileio , G. and Levitt , M.H. ( 2015 ). Theory of long-lived nuclear spin states in methyl groups and quantum-rotor induced polarisation . J. Chem. Phys . 142 ( 4 ): 044506 . Kaptein , R. ( 1972, September ). Chemically induced dynamic nuclear polarization. VIII. Spin dynamics and diffusion of radical pairs . J. Am. Chem. Soc . 94 ( 18 ): 6251 – 6262 . ISSN 0002-7863. Bowers , C.R. and Weitekamp , D.P. ( 1987 September). Parahydrogen and synthesis allow dramatically enhanced nuclear alignment . J. Am. Chem. Soc . 109 ( 18 ): 5541 – 5542 . ISSN 0002-7863. Adams , R.W. , Aguilar , J.A. , Atkinson , K.D. , Cowley , M.J. , Elliott , P.I. , Duckett , S.B. , Green , G.G. , Khazal , I.G. , López-Serrano , J. and Williamson , D.C ( 2009 March). Reversible interactions with para-hydrogen enhance NMR sensitivity by polarization transfer . Science 323 ( 5922 ): 1708 – 1711 . Levitt , M.H. ( 2007 ). Spin Dynamics. Basics of Nuclear Magnetic Resonance . Wiley, Chichester, second edition. ISBN 0-471-48921-2. Tayler , M.C. , Theis , T. , Sjolander , T.F. , Blanchard , J.W. , Kentner , A. , Pustelny , S. , Pines , A. and Budker , D. ( 2017 September). Invited review article: instrumentation for nuclear magnetic resonance in zero and ultralow magnetic field . Rev. Sci. Instrum . 88 ( 9 ): 091101. ISSN 0034-6748. Jiang , M. , Bian , J. , Li , Q. , Wu , Z. , Su , H. , Xu , M. , Wang , Y. , Wang , X. and Peng , X. ( 2021 January). Zero- to ultralow-field nuclear magnetic resonance and its applications. Fundam. Res. 1 ( 1 ): 68 – 84 . ISSN 2667-3258. Jeener , J. and Alewaeters , G. ( 2016 May). “Pulse pair technique in high resolution NMR” a reprint of the historical 1971 lecture notes on two-dimensional spectroscopy. Prog. Nucl. Magn. Reson. Spectrosc . 94–95: 75–80. ISSN 0079-6565. Aue , W.P. , Bartholdi , E. and Ernst , R.R. ( 1976 ). Two-dimensional spectroscopy. Application to nuclear magnetic resonance . J. Chem. Phys . 64 : 2229 . Frydman , L. , Scherf , T. and Lupulescu , A. ( 2002 ). The acquisition of multidimensional NMR spectra within a single scan . Proc. Natl. Acad. Sci. USA 99 ( 25 ): 15858 – 15862 . Dumez , J.N. ( 2018 December). Spatial encoding and spatial selection methods in high-resolution NMR spectroscopy. Prog. Nucl. Magn. Reson. Spectrosc . 109: 101–134. ISSN 0079-6565. States , D.J. , Haberkorn , R.A. and Ruben , D.J. ( 1982 June). A two-dimensional nuclear overhauser experiment with pure absorption phase in four quadrants. J. Magn. Reson. (1969) , 48 ( 2 ): 286 – 292 . ISSN 0022-2364. Wokaun , A. and Ernst , R.R. ( 1978 August). The use of multiple quantum transitions for relaxation studies in coupled spin systems . Mol. Phys . 36 ( 2 ): 317 – 341 . ISSN 0026-8976. Mueller , L. ( 1979 August). Sensitivity enhanced detection of weak nuclei using heteronuclear multiple quantum coherence . J. Am. Chem. Soc . 101 ( 16 ): 4481 – 4484 . ISSN 0002-7863. Kumar , A. , Welti , D. and Ernst , R.R. ( 1975 April). NMR Fourier zeugmatography . J. Magn. Reson. (1969) , 18 ( 1 ): 69 – 83 . ISSN 0022-2364. Jeener , J.M.B.H. , Meier , B.H. , Bachmann , P. and Ernst , R.R. ( 1979 ). Investigation of exchange processes by 2-dimensional NMR spectroscopy. J. Chem. Phys . 71 ( 11 ): 4546 – 4553 . ISSN 0021-9606. Solomon , I. ( 1955 July). Relaxation processes in a system of two spins . Phys. Rev . 99 ( 2 ): 559 – 565 . Kumar , A. , Ernst , R.R. and Wthrich , K. ( 1980 July). A two-dimensional nuclear Overhauser enhancement (2D NOE) experiment for the elucidation of complete proton-proton cross-relaxation networks in biological macromolecules . Biochem. Biophys. Res. Commun . 95 ( 1 ): 1 – 6 . ISSN 0006-291X. Oschkinat , H. , Griesinger , C. , Kraulis , P.J. , Srensen , O.W. , Ernst , R.R. , Gronenborn , A.M. and Clore , G.M. Three-dimensional NMR spectroscopy of a protein in solution . Nature , 332 ( 6162 ): 374 – 376 . ISSN 1476-4687. Bodenhausen , G. ( 2021 January). Early days of two-dimensional ion cyclotron resonance . Molecule , 26 ( 11 ): 3381 . Zanni , M.T. and Hochstrasser , R.M. ( 2001 September). Two-dimensional infrared spectroscopy: a promising new method for the time resolution of structures . Curr. Opin. Struct. Biol . 11 ( 5 ): 516 – 522 . ISSN 0959-440X. Cahoon , J.F. , Sawyer , K.R. , Schlegel , J.P. and Harris , C.B. ( 2008 March). Determining transition-state geometries in liquids using 2D-IR. Science . Finneran , I.A. , Welsch , R. , Allodi , M.A. , Miller III , T.F. and Blake , G.A. ( 2016 June). Coherent two-dimensional terahertz-terahertz-Raman spectroscopy . PNAS 113 ( 25 ): 6857 – 6861 . ISSN 0027-8424, 1091-6490. Cho , M. ( 2008 April). Coherent two-dimensional optical spectroscopy . Chem. Rev . 108 ( 4 ): 1331 – 1418 . ISSN 0009-2665. Mukamel , S. ( 2000 October). Multidimensional femtosecond correlation spectroscopies of electronic and vibrational excitations . Annu. Rev. Phys. Chem . 51 ( 1 ): 691 – 729 . ISSN 0066-426X. Two‐Dimensional (2D) NMR Methods, First ReferencesRelatedInformation

科研通智能强力驱动
Strongly Powered by AbleSci AI
科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
过时的手套完成签到,获得积分10
1秒前
情怀应助过时的手套采纳,获得10
4秒前
管管吃饱辣完成签到 ,获得积分20
6秒前
7秒前
7秒前
MADMAX完成签到,获得积分10
7秒前
郭博发布了新的文献求助10
11秒前
14秒前
小圆圈发布了新的文献求助100
29秒前
33秒前
38秒前
Ava应助科研通管家采纳,获得10
1分钟前
null应助科研通管家采纳,获得10
1分钟前
null应助科研通管家采纳,获得10
1分钟前
科研通AI2S应助科研通管家采纳,获得10
1分钟前
科研通AI6应助科研通管家采纳,获得10
1分钟前
顾矜应助科研通管家采纳,获得20
1分钟前
jarrykim完成签到,获得积分10
1分钟前
1分钟前
上官若男应助LukeLion采纳,获得10
1分钟前
所所应助轻松一曲采纳,获得10
1分钟前
每㐬山风完成签到 ,获得积分10
1分钟前
1分钟前
LukeLion发布了新的文献求助10
1分钟前
1分钟前
微醺潮汐发布了新的文献求助10
1分钟前
852应助dbyy采纳,获得10
2分钟前
灯光师完成签到,获得积分10
2分钟前
2分钟前
2分钟前
轻松一曲发布了新的文献求助10
2分钟前
轻松一曲完成签到,获得积分10
2分钟前
动听的又亦完成签到 ,获得积分10
2分钟前
2分钟前
du关闭了du文献求助
2分钟前
答辩完成签到 ,获得积分10
3分钟前
3分钟前
领导范儿应助LiuHD采纳,获得10
3分钟前
JoeyJin完成签到,获得积分10
3分钟前
科目三应助zhang采纳,获得10
3分钟前
高分求助中
(应助此贴封号)【重要!!请各用户(尤其是新用户)详细阅读】【科研通的精品贴汇总】 10000
Encyclopedia of Reproduction Third Edition 3000
《药学类医疗服务价格项目立项指南(征求意见稿)》 1000
花の香りの秘密―遺伝子情報から機能性まで 800
1st Edition Sports Rehabilitation and Training Multidisciplinary Perspectives By Richard Moss, Adam Gledhill 600
Chemistry and Biochemistry: Research Progress Vol. 7 430
Bone Marrow Immunohistochemistry 400
热门求助领域 (近24小时)
化学 材料科学 生物 医学 工程类 计算机科学 有机化学 物理 生物化学 纳米技术 复合材料 内科学 化学工程 人工智能 催化作用 遗传学 数学 基因 量子力学 物理化学
热门帖子
关注 科研通微信公众号,转发送积分 5628131
求助须知:如何正确求助?哪些是违规求助? 4715760
关于积分的说明 14963712
捐赠科研通 4785826
什么是DOI,文献DOI怎么找? 2555337
邀请新用户注册赠送积分活动 1516672
关于科研通互助平台的介绍 1477224