电致发光
发光
材料科学
圆极化
光电子学
光化学
光学
纳米技术
化学
物理
微带线
图层(电子)
作者
Letian Xu,Hao Liu,Xiaoluo Peng,Pingchuan Shen,Ben Zhong Tang,Zujin Zhao
标识
DOI:10.1002/anie.202300492
摘要
Circularly polarized electroluminescence (CP-EL) is generally produced in organic light-emitting diodes (OLEDs) based on special CP luminescent (CPL) materials, while common achiral luminescent materials are rarely considered to be capable of direct producing CP-EL. Herein, near ultraviolet CPL materials with high photoluminescence quantum yields and good CPL dissymmetry factors are developed, which can induce blue to red CPL for various achiral luminescent materials. Strong near ultraviolet CP-EL with the best external quantum efficiencies (ηext s) of 9.0 % and small efficiency roll-offs are achieved by using them as emitters for CP-OLEDs. By adopting them as hosts or sensitizers, commercially available yellow-orange achiral phosphorescence, thermally activated delayed fluorescence (TADF) and multi-resonance (MR) TADF materials can generate intense CP-EL, with high dissymmetry factors and outstanding ηext s (30.8 %), demonstrating a simple and universal avenue towards efficient CP-EL.
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