Alcohol‐Assisted Synthesis of Sheet‐Like ZSM‐5 Zeolites with Controllable Aspect Ratios

Abstract Sheet‐like ZSM‐5 has been regarded as a promising material for catalytic applications due to its diffusion superiority. However, it still remains a challenge to obtain a desirable sheet‐like morphology because of the complex synthesis process of zeolites. Here, a facile strategy for synthesizing sheet‐like ZSM‐5 is developed by only adding ethanol as zeolite growth modifier in the synthesis gel. It is thought that ethanol might be preferentially absorbed on the {010} surface of zeolite crystals, interact with the exposed silicon hydroxyl groups on the crystal {010} facet, and suppress the growth of b axis, resulting in the sheet‐like shape. Through finely tunning synthesis parameters, sheet‐like ZSM‐5 crystals with thin b‐axis thickness of 90 nm and different aspect ratios could be obtained. Owing to its shorter diffusion path and optimized acidity, sheet‐like ZSM‐5 exhibits better catalytic performance than conventional ZSM‐5 in the alkylation of benzene with ethanol.