硼酸
硼
硼同位素
同位素
红外光谱学
光谱学
分析化学(期刊)
化学
傅里叶变换红外光谱
衰减全反射
质谱法
离子
色谱法
光学
有机化学
物理
量子力学
标识
DOI:10.1007/s10967-022-08746-8
摘要
Due to the low atomic mass of boron, its different isotopes (B-10 and B-11) leads to a measurable impact on vibrational spectra. Indeed, a shift in the asymmetric stretching of the dissolved species has been found using attenuated total reflectance infrared spectroscopy, and those of acid species is higher than those of the borate ion (41 cm−1 vs. 20 cm−1, respectively). A calibration from pure B-10 to pure B-11 boric acid has been performed, leading to an accuracy higher than 0.5% on the B-10 percentage of 0.1 M solution of mixtures of the two isotopes.
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