Simultaneous enhancement of dielectric properties and temperature stability in BaTiO3‐based ceramics enabling X8R multilayer ceramic capacitor

Abstract Modified BaTiO 3 ceramics that possess high dielectric permittivity and acceptable temperature stability have been widely utilized as multilayer ceramic capacitors (MLCCs) for high‐frequency bypass and power filtering in automotive applications. However, since the increasing demand for high‐capacity and small‐size, high‐permittivity materials that can serve as dielectric layers in MLCCs are urgently required. In this work, we design and fabricate a special BaTiO 3 ‐0.03Mg‐0.02Y‐0.02CaZrO 3 ceramic with a high dielectric permittivity of 3000 and the dielectric variation below ±13% in the temperature range of ‐55–150°C, fulfilling the requirements of X8R capacitors. To achieve these results, we employed grain size engineering and cation doping, using BaTiO 3 precursors with a particle size of 240 nm to prepare the BaTiO 3 ‐based ceramics with fine grains, while Mg and Y co‐doping was used for improving the temperature stability due to dielectric dispersion. Utilizing these high‐permittivity BaTiO 3 ‐based materials, we fabricated MLCCs that satisfy the X8R criterion, possessing a high dielectric constant of 2950 and a high breakdown field (410 kV/cm).