1,2‐Arylsulfonylation of Vinyl Ethers and Esters Enabled by Dual Ni Catalysis

Abstract A dual photocatalytic sulfonylation‐arylation of electron‐rich alkenes is described. By combining sulfinate salts, (hetero)‐aryl‐bromides and 2,3‐dihydrofuran under Ru and Ni dual catalysis, over 35 examples of aryl‐sulfonylated scaffolds could be obtained in good to excellent yields, under mild reaction conditions and high diastereoselectivity.