Synergistic Ion Diffusion in Lithium Titanium Phosphate Conductors: A Tale from Solo to Ensemble

快离子导体 离子 化学物理 中子衍射 离子键合 离子电导率 电解质 离子运输机 锂(药物) 材料科学 扩散 化学 结晶学 晶体结构 物理化学 热力学 物理 内分泌学 有机化学 医学 电极
作者
Xinyu Zhang,Denys S. Butenko,Lei Gao,Xinyan Ye,Bolong Hong,Songbai Han,Wei Xia,Shaofei Wang,Yang Sun,Yusheng Zhao,Jinlong Zhu
出处
期刊:Chemistry of Materials [American Chemical Society]
卷期号:35 (11): 4541-4548 被引量:5
标识
DOI:10.1021/acs.chemmater.3c00856
摘要

The rational design of solid electrolytes for the next-generation batteries entails an accurate understanding of ionic transport mechanisms. To elucidate the detailed ion hopping processes in different coordinate environments, two solid electrolytes, LiTi2(PO4)3 and Li3Ti2(PO4)3, with the same NASICON-type framework but different sites for accommodating mobile ions, were synthesized and investigated by in situ neutron diffraction and theoretical calculations. The temperature-dependent anisotropic thermal vibrational ellipsoids and migration paths from the maximum entropy method (MEM) indicated that Li ions move faster at higher coordinate architectures, exhibiting three-dimensional (3D) diffusion pathways. In this rhombohedral structure, "one" node (M1 site) out of "three" interconnected transition sites was found to be the lithium configuration of NASICON. Li ions located at the nodes along the 3D pathway in LiTi2(PO4)3 can only drive out another Li-ion species at the node site, while Li ions located at transition sites between two nodes in Li3Ti2(PO4)3 have repulsive force from their five surrounding Li ions. These different configurations lead to distinct overall transport modes. In LiTi2(PO4)3, concerted Li ions transport along a separated chain, while in Li3Ti2(PO4)3, concerted motion occurs along multiple cooperating chains in the 3D channels. Theoretical calculations further indicated that a larger diffusion bottleneck size of Li3Ti2(PO4)3 enables lower hopping energy compared to LiTi2(PO4)3. This study clarifies the detailed ionic hopping processes and the underlying structure–conductivity relationships. Overall, these results elucidate the synergistic events in Li-ion hopping from thermodynamic and kinetic points of view, which will greatly benefit the rational design of solid electrolytes for next-generation batteries.
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