Coprecipitation of Fe/Cr Hydroxides at Organic–Water Interfaces: Functional Group Richness and (De)protonation Control Amounts and Compositions of Coprecipitates

共沉淀 质子化 吸附 化学 腐植酸 无机化学 核化学 有机化学 氢氧化物 离子 肥料
作者
Yandi Hu,Xulin Jiang,Suona Zhang,Dawei Cai,Zehao Zhou,Chuan Liu,Xiaobing Zuo,Sang Soo Lee
出处
期刊:Environmental Science & Technology [American Chemical Society]
卷期号:58 (19): 8501-8509 被引量:11
标识
DOI:10.1021/acs.est.4c01245
摘要

Iron/chromium hydroxide coprecipitation controls the fate and transport of toxic chromium (Cr) in many natural and engineered systems. Organic coatings on soil and engineered surfaces are ubiquitous; however, mechanistic controls of these organic coatings over Fe/Cr hydroxide coprecipitation are poorly understood. Here, Fe/Cr hydroxide coprecipitation was conducted on model organic coatings of humic acid (HA), sodium alginate (SA), and bovine serum albumin (BSA). The organics bonded with SiO2 through ligand exchange with carboxyl (–COOH), and the adsorbed amounts and pKa values of –COOH controlled surface charges of coatings. The adsorbed organic films also had different complexation capacities with Fe/Cr ions and Fe/Cr hydroxide particles, resulting in significant differences in both the amount (on HA > SA(–COOH) ≫ BSA(–NH2)) and composition (Cr/Fe molar ratio: on BSA(–NH2) ≫ HA > SA(–COOH)) of heterogeneous precipitates. Negatively charged –COOH attracted more Fe ions and oligomers of hydrolyzed Fe/Cr species and subsequently promoted heterogeneous precipitation of Fe/Cr hydroxide nanoparticles. Organic coatings containing –NH2 were positively charged at acidic pH because of the high pKa value of the functional group, limiting cation adsorption and formation of coprecipitates. Meanwhile, the higher local pH near the –NH2 coatings promoted the formation of Cr(OH)3. This study advances fundamental understanding of heterogeneous Fe/Cr hydroxide coprecipitation on organics, which is essential for successful Cr remediation and removal in both natural and engineered settings, as well as the synthesis of Cr-doped iron (oxy)hydroxides for material applications.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
maizhan完成签到,获得积分10
刚刚
默认用户名完成签到,获得积分10
1秒前
2秒前
leei完成签到,获得积分10
3秒前
meng123发布了新的文献求助10
3秒前
小马甲应助c123采纳,获得10
4秒前
莎莎士比亚完成签到,获得积分10
6秒前
LOST完成签到 ,获得积分10
6秒前
7秒前
袁凯文发布了新的文献求助10
7秒前
共享精神应助老菜鸟321采纳,获得10
7秒前
WUWEI发布了新的文献求助10
8秒前
xiaoW完成签到,获得积分10
8秒前
10秒前
牛太虚完成签到,获得积分10
10秒前
SciGPT应助科多兽骑士采纳,获得10
10秒前
12秒前
gjm完成签到,获得积分10
12秒前
SciGPT应助zj采纳,获得10
13秒前
Ava应助阿湫采纳,获得10
13秒前
meng123完成签到,获得积分20
14秒前
x5kyi完成签到,获得积分10
15秒前
爆米花应助肖遥采纳,获得10
16秒前
Xx完成签到,获得积分10
16秒前
16秒前
19秒前
烟里戏完成签到 ,获得积分10
21秒前
shuangfeng1853完成签到 ,获得积分10
21秒前
林子青发布了新的文献求助10
21秒前
22秒前
aa完成签到,获得积分10
22秒前
CXC完成签到,获得积分10
22秒前
24秒前
Zzz发布了新的文献求助10
24秒前
上官若男应助袁凯文采纳,获得10
25秒前
25秒前
褚晣完成签到,获得积分10
25秒前
ATTENTION完成签到,获得积分10
26秒前
26秒前
周欣玙完成签到,获得积分10
26秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
Research on Disturbance Rejection Control Algorithm for Aerial Operation Robots 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038524
求助须知:如何正确求助?哪些是违规求助? 3576221
关于积分的说明 11374737
捐赠科研通 3305912
什么是DOI,文献DOI怎么找? 1819354
邀请新用户注册赠送积分活动 892688
科研通“疑难数据库(出版商)”最低求助积分说明 815048