海水
材料科学
氧气
析氧
电催化剂
兴奋剂
分解水
纳米纤维
化学工程
催化作用
无机化学
纳米技术
海洋学
物理化学
光电子学
电化学
有机化学
化学
电极
工程类
地质学
光催化
生物化学
作者
Yajuan Pan,Zhichong Wang,Kaixuan Wang,Qing Ye,Baoshou Shen,Fangshe Yang,Yongliang Cheng
标识
DOI:10.1002/adfm.202402264
摘要
Abstract The exploitation of highly activity oxygen evolution reaction (OER) electrocatalysts is critical for the application of electrocatalytic water splitting. Triggering the lattice oxygen mechanism (LOM) is expected to provide a promising pathway to overcome the sluggish OER kinetics, however, effectively enhancing the involvement of lattice oxygen remains challenging. In this study, the fabrication of B, Fe co‐doped CoP (B, Fe─CoP) nanofibers is reported, which serve as highly efficient OER electrocatalyst through phosphorization and boronation treatment of Fe‐doped Co 3 O 4 nanofibers. Experimental results combined with theoretical calculations reveal that simultaneous incorporation of both B and Fe can more effectively trigger the participation of lattice oxygen in CoFe oxyhydroxides reconstructed from B, Fe─CoP nanofibers compared to incorporating only B or Fe. Therefore, the optimized B, Fe─CoP nanofibers exhibit superb OER activity with low overpotentials of 361 and 376 mV at 1000 mA cm −2 in alkaline freshwater and alkaline natural seawater, respectively. The present work provides significant guidelines and innovative design concepts for the development of OER electrocatalysts following the LOM pathway.
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