六价铬
光催化
材料科学
铬
铟
硫化物
金属
铬酸盐转化膜
贵金属
异质结
化学工程
纳米技术
催化作用
冶金
化学
光电子学
工程类
生物化学
作者
Huoshuai Huang,Xin Jiang,Najun Li,Dongyun Chen,Qingfeng Xu,Hua Li,Jinghui He,Jianmei Lu
标识
DOI:10.1016/j.apcatb.2020.119754
摘要
The conversion of highly toxic heavy metal hexavalent chromium (Cr(VI)) in the natural environment into low-toxic trivalent chromium (Cr(III)) is one of the research topics of great concern. Herein, a binary noble-metal-free photocatalyst consisting of ultrathin MXene (Ti3C2) and indium sulfide (In2S3) is prepared for ultrafast photocatalytic reduction of Cr(VI) to Cr(III) under visible light. A simple electrostatic assembly and reflow method uniformly coats the In2S3 nanoflakes on the surface of hollow Ti3C2 nanospheres, which effectively boost the separation of charges and thus enhance the photocatalytic performance. Thus, the prepared heterojunction can reduce Cr(VI) to Cr(III) completely within 6 min with an ultrafast rate constant of k = 0.739 min−1. More importantly, the appropriate band structure ensures the stable existence of Cr(III). Therefore, it provides a new insight for economic MXene-based binary photocatalysts for efficient environmental remediation.
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