Temperature‐Dependent Electrochemical Properties and Electrode Kinetics of Na3V2(PO4)2O2F Cathode for Sodium‐Ion Batteries with High Energy Density

Phosphate cathode materials are practical for use in sodium-ion batteries (SIBs) owing to their high stability and long-term cycle life. In this work, the temperature-dependent properties of the phosphate cathode Na3 V2 (PO4 )2 O2 F (NVPOF) are studied in a wide temperature range from -25 to 55 °C. Upon cycling at general temperature (above 0 °C), the NVPOF cathode retains an excellent charge/discharge performance, and the rate capability is noteworthy, indicating that NVPOF is a competitive candidate as a temperature-adaptive cathode for SIBs. Upon decreasing the temperature below 0 °C, the cell performance deteriorates, which may be caused by the electrolyte and Na electrode, based on the study of ionic conductivity and electrode kinetics. This work proposes a new breakthrough point for the development of SIBs with high performance over a wide temperature range for advanced power systems.