Building a Cycle-Stable Fe–Si Alloy/Carbon Nanocomposite Anode for Li-Ion Batteries through a Covalent-Bonding Method

Si is being intensively developed as a safe and high-performance anode for next-generation Li-ion batteries (LIBs); however, its battery application still remains challenging because of its low cycling Coulombic efficiency. To address this issue, we chose a conjugated polymer, polynaphthalene, as a carbon precursor and a low-cost commercial ferrosilicon (Fe-Si) alloy as the active phase to prepare a Fe-Si/C nanocomposite with a core-shell-like architecture through sand milling-assisted covalent-bonding method, followed by a carbonization reaction, thus forming a covalently bonded carbon coating on the surfaces of Fe-Si alloy nanoparticles. Benefitting from the greatly reduced volumetric expansion of Fe-Si alloy cores in the lithiation process and the stable interface provided by the outer carbon shell, the thus-prepared Fe-Si/C nanocomposite exhibits a high structural stability in repeated charge/discharge cycles. The experimental results reveal that the Fe-Si/C composite anode can demonstrate a high reversible capacity of 1316.2 mA h g^-1 with an active mass utilization of 82.6%, a long-term cycle stability of more than 1000 cycles even at a considerably high current rate of 2.0 A g^-1, and, in particular, a high cycling Coulombic efficiency of 99.7%, showing great prospect for application in practical LIBs.