A Symmetric All‐Organic Proton Battery in Mild Electrolyte

All-organic proton batteries are attracting extensive attention due to their sustainability merits and excellent rate capability. Generally, strong acids (e.g. H2 SO4 ) have to be employed as the electrolytes to provide H+ for all-organic proton batteries due to the high H+ intercalation energy barrier. Until now, the design of all-organic proton batteries in mild electrolytes is still a challenge. Herein, a poly(2,9-dihydroquinoxalino[2,3-b]phenazine) (PO) molecule was designed and synthesized, where the adjacent C=N groups show two different chemical environments, resulting in two-step redox reactions. Moreover, the two reactions possess considerable voltage difference because of the large LUMO energy gap between PO and its reduction product. More impressively, the C=N groups endow the π-conjugated PO molecule with H+ uptake/removal in the ZnSO4 electrolyte. As a result, a symmetric all-organic proton battery is achieved in a mild electrolyte for the first time, which exhibits enhanced electrochemical performance and also broadens the chemistry of proton-based batteries.