Highly efficient and selective electrocatalytic hydrogen peroxide production on Co-O-C active centers on graphene oxide

Abstract Electrochemical oxygen reduction provides an eco-friendly synthetic route to hydrogen peroxide (H 2 O 2 ), a widely used green chemical. However, the kinetically sluggish and low-selectivity oxygen reduction reaction (ORR) is a key challenge to electrochemical production of H 2 O 2 for practical applications. Herein, we demonstrate that single cobalt atoms anchored on oxygen functionalized graphene oxide form Co-O-C@GO active centres (abbreviated as Co 1 @GO for simplicity) that act as an efficient and durable electrocatalyst for H 2 O 2 production. This Co 1 @GO electrocatalyst shows excellent electrochemical performance in O 2 -saturated 0.1 M KOH, exhibiting high reactivity with an onset potential of 0.91 V and H 2 O 2 production of 1.0 mg cm −2 h −1 while affording high selectivity of 81.4% for H 2 O 2 . Our combined experimental observations and theoretical calculations indicate that the high reactivity and selectivity of Co 1 @GO for H 2 O 2 electrogeneration arises from a synergistic effect between the O-bonded single Co atoms and adjacent oxygen functional groups (C-O bonds) of the GO present in the Co-O-C active centres.