假电容
共价键
共价有机骨架
超级电容器
异质结
电极
材料科学
电化学
化学工程
纳米技术
多孔性
比表面积
化学
有机化学
光电子学
电容
复合材料
催化作用
物理化学
工程类
作者
Qian Geng,Haichao Wang,Wei Yang,Liping Lv,Shuangqiang Chen,Weiwei Sun,Yong Wang
标识
DOI:10.1002/celc.202200340
摘要
Abstract Heterostructures based on covalent organic frameworks (COFs) and conductive materials have attracted more attentions to effectively apply COF‐related materials for supercapacitor. Here, the as‐prepared amino‐modified Ti 3 C 2 MXene nanosheets are adopted to support the in‐situ growth of anthraquinone‐based COFs (AQ‐COF) to fabricate the heterostructures of COFs uniformly dispersed on surface of MXene, based on the covalent interaction between terminal C=O groups of COFs and amino units of MXene. Besides, the morphology and porous structures of COF@MXene heterostructures are optimized by controlling the amounts of MXene nanosheets. Combining the superiority from the two‐dimensional structure with high conductivity of MXene and porous structure with abundant redox‐active groups inherited from AQ‐COF, the COF@MXene‐15 heterostructure electrode delivers large surface area with optimal porous structures, leading to the maximally‐activated C=O units for charge‐storage and capacitance‐controlled electrochemical kinetics. Improved specific capacitance (290 F g −1 at 0.5 A g −1 ) and rate capability can be achieved for the COF@MXene‐15 heterostructure as the electrode for supercapacitor in Na 2 SO 4 electrolyte. It is the first time to report the heterostructure of COFs and MXene as the electrode for supercapacitor, and this work would promote further application of COFs and related materials for other energy‐storage systems.
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