Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study

Angewandte Chemie International EditionVolume 47, Issue 22 p. 4100-4105 Communication Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study† Franck Millange Dr., Franck Millange Dr. [email protected] Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorChristian Serre Dr., Christian Serre Dr. Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorNathalie Guillou Dr., Nathalie Guillou Dr. Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorGérard Férey Prof., Gérard Férey Prof. Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorRichard I. Walton Dr., Richard I. Walton Dr. [email protected] Department of Chemistry, The University of Warwick, Coventry CV4 7AL, UK, Fax: (+44) 247-652-4112Search for more papers by this author Franck Millange Dr., Franck Millange Dr. [email protected] Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorChristian Serre Dr., Christian Serre Dr. Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorNathalie Guillou Dr., Nathalie Guillou Dr. Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorGérard Férey Prof., Gérard Férey Prof. Institut Lavoisier, Université de Versailles St-Quentin en Yvelines (UMR CNRS 8180), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax: (+33) 139-254-358Search for more papers by this authorRichard I. Walton Dr., Richard I. Walton Dr. [email protected] Department of Chemistry, The University of Warwick, Coventry CV4 7AL, UK, Fax: (+44) 247-652-4112Search for more papers by this author First published: 09 May 2008 https://doi.org/10.1002/anie.200705607Citations: 186 † We thank the STFC for provision of beam time at the Daresbury SRS. We are also indebted to the ESRF in Grenoble for providing beam time and for the assistance of Yaroslav Filinchuk during the experiments in collecting powder XRD data. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Breathing space: Time-resolved diffraction studies of the breathing of metal–organic frameworks in the presence of liquids reveal rapid exchange of one guest molecule by another. In some cases this occurs by direct exchange (as shown for water by pyridine), in others with the transient appearance of crystalline intermediates corresponding to partially expanded forms. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z705607_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume47, Issue22May 19, 2008Pages 4100-4105 RelatedInformation