光致聚合物
3D打印
立体光刻
数字光处理
铸造
材料科学
聚脲
热致变色
3d打印机
化学工程
计算机科学
复合材料
有机化学
聚氨酯
工程类
化学
聚合物
计算机视觉
机械工程
聚合
投影机
作者
Guoqiang Zhu,Jinshuai Zhang,Jia Huang,Yuhao Qiu,Meiting Liu,Jinni Yu,Chengguo Liu,Qianqian Shang,Yun Hu,Lihong Hu,Yonghong Zhou
标识
DOI:10.1016/j.cej.2022.139401
摘要
Developing recyclable biobased photopolymers for UV-curable 3D printing is of great significance for sustainable development of 3D printing industry. In this work, novel recyclable and reprintable castor oil (CO)-based photopolymers for digital light processing (DLP) 3D printing were developed via hindered urea bonds, a type of dissociating dynamic covalent bonds. Remarkably, the printed objects could be recycled in 4 h at 90 °C or 2 h at 100 °C without any catalysts or solvents, and the recycled resins had similar physiochemical properties, polymerization kinetics, and printing resolutions as the original resin. Furthermore, reprintable sacrificial molds and thermochromic materials were achieved with the optimal biobased resin, which can be used in complicated model casting and information encryption/anti-counterfeiting areas. In particular, thermochromic microcapsules could be recycled nondestructively from the printed thermochromic materials and reused in DLP 3D printing.
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