Expedient access to α-(hetero)aryl-α-keto-1,3-diamines via redox-neutral photocatalyzed reactions of N-vinylimides with α-aminoalkyl radicals

Herein we report a novel acyl migration protocol based on reductive radical-polar crossover process enabled by redox-neutral photocatalysis. Employing tertiary amines or α-silylamines as the radical sources, modular access to...