Manipulating the Charge Carriers Through Functionally Bridged Components Advances Low‐Cost Organic Solar Cells with Green Solvent Processing

Abstract Organic solar cell (OSC) development continues to demonstrate impressive device efficiency improvements. However, the materials synthetic simplicity essential to industrialization remains seriously lacking attention, imparting inferior performance records in low‐cost devices. Hence, low bandgap and completely non‐fused electron acceptors (CNFEAs) having simple molecular structures are investigated herein. In contrast to typically explored fused‐ring acceptors with smaller backbone conformational variations, minimizing the interface recombination sites through a greater extent of localized domains is identified as more critical in CNFEAs, leading to remarkable fill factors ( FF s) approaching 75%, among the highest currently realized for low‐cost systems. However, this comes with diminishing charge generation efficiency. The general ternary blend optimization strategy modifying the morphology of host components is limited in preserving such remarkably high FF s. To suppress the trade‐off while keeping notable FF s, a new perspective of constructing functionally bridged components based on optical, electronic, and thermodynamic properties is introduced here. Specifically, charge generation is unrestrained from the host acceptor localized domains through the introduction of a “bridge” component while also taking advantage of the configuration to channel polarons toward the efficient transport moieties of the host components. Accordingly, this work incubates understanding‐guided optimizations toward the advancement of more practical devices.