超级电容器
电流密度
介孔材料
电容
比表面积
化学工程
材料科学
功率密度
碳纤维
多孔性
氢氧化钾
电极
碳酸钾
纳米技术
化学
复合材料
有机化学
催化作用
复合数
功率(物理)
物理
物理化学
量子力学
工程类
作者
Kaiming Dong,Jiajun Wang,Feiqiang Guo,Sha Li,Biao Tang,Lingwei Kong,Ning Zhao,Yue Hou
标识
DOI:10.1016/j.diamond.2023.110531
摘要
Biomass-derived carbons with porous structures and abundant surface functional groups have been regarded as a competitive electrode material for supercapacitors due to their renewability and easily adjustable porosity. The low-cost and environmentally friendly synthesis method of O and P co-doped hierarchical porous carbon nanosheets from waste coconut shells using potassium bicarbonate (KHCO3) and potassium dihydrogen phosphate (KH2PO4) as both activators and co-doped agents have been investigated for high-performance supercapacitors. Under an appropriate KH2PO4 dosage, the pore structure of PAC-0.9 contains micropores, mesopores and macropores, and its specific surface area is 892.06 m2 g−1. The specific capacitance of PAC-0.9 in three electrode system reached 371.63 F g−1 at a current density of 0.5 A g−1, and remained at 223.25 F g−1 even for a current density of 30 A g−1. The symmetrical supercapacitor assembled with PAC-0.9 as the electrode achieved an energy density of 9.15 Wh kg−1 at a power density of 500 W kg−1. At a current density of 5 A g−1, the specific capacitance of PAC-SSC can still retain 96.23 % after 10,000 charge-discharge cycles.
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