Selective Electrosynthesis of Urea via C−N Coupling: Current Status, Challenges and Future Prospects

Abstract Selective electrosynthesis of urea from carbon source (CO 2 ) and nitrogen (N 2 , NO 3 − , NO 2 − ) source provides a sustainable strategy for production of essential nitrogen‐based fertilizers. The traditional technology of urea synthesis employs two consecutive processes, synthesis of NH 3 from N 2 +H 2 and urea from NH 3 +CO 2 , which always involves high energy consumption and environmental concerns. By contrast, urea electrosynthesis avoids the above harsh steps and meanwhile has higher atomic economy. Herein, we present a comprehensive review on the progress and prospect of urea electrosynthesis from abundant carbon and nitrogen sources via coupling of C−N under ambient conditions, and also discuss the mechanism researches, strategies of substrates activation, current challenges and future opportunities of urea electrosynthesis. The urea electrosynthesis via C−N coupling realizes abundant and low‐cost inorganic carbon and nitrogen sources for efficient resource utilization and provides guidance and reference for C−C, C−S or other coupling reactions.