Sialon-SiC composite powders were synthesized from kyanite tailings through the carbothermal reduction nitridation (CRN) technique. Using Sialon-SiC composites to substitute Si 3 N 4 composites via the CRN technique synthesize Sialon/Si 3 N 4 -SiC composite refractories. The phase composition, cross section morphology, and the substituent amount of Sialon-SiC composites impact on refractories mechanical properties were investigated, respectively. The optimized synthesis temperature for the CRN reaction was found to be 1550 °C for 4 h with the excess carbon 20%. The substituent amount of Sialon-SiC was 25%, the mechanical properties of Sialon/Si 3 N 4 -SiC composite refractories reached optimal performance, which bending strength value was 41.8 MPa and compression strength value was 61.6 MPa.