浸出(土壤学)
镁
硫酸盐
硫酸铵
稀土元素
吸附
无机化学
化学
稀土
材料科学
冶金
矿物学
地质学
土壤科学
土壤水分
有机化学
作者
Yanfei Xiao,Yingying Chen,Zongyu Feng,Xiaowei Huang,Huang Li,Zhiqi Long,Dali Cui
标识
DOI:10.1016/s1003-6326(15)64022-5
摘要
Magnesium sulfate was proposed to be leaching agent to deal with the ion-adsorption type rare earths ore to reduce or even eliminate ammonia–nitrogen emissions. The effects of temperature, particle size and stirring speed on rare earth leaching process and the leaching behaviors of the single rare earth element were investigated in order to reveal the rare earth leaching characteristics. Besides, the comparison of leaching effects between magnesium sulfate and ammonium sulfate was also studied. The results showed that the rare earth leaching process could be well described with inner diffusion control model and the apparent activation energy was 9.48 kJ/mol. The leaching behaviors of the single rare earth element were brought into correspondence with rare earths. Moreover, when the concentration of leaching agent was 0.20 mol/L, the rare earth leaching efficiency could all reach above 95% and the leaching efficiency of aluminum impurities could be restrained by 10% using magnesium sulfate compared with ammonium sulfate.
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