Lithium Iron Borates as High‐Capacity Battery Electrodes

Advanced MaterialsVolume 22, Issue 32 p. 3583-3587 Communication Lithium Iron Borates as High-Capacity Battery Electrodes Atsuo Yamada, Corresponding Author Atsuo Yamada [email protected] Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Building 5–607, 7–3-1 Hongo, Bunkyo-ku, Tokyo 113–8656 (Japan)Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Building 5–607, 7–3-1 Hongo, Bunkyo-ku, Tokyo 113–8656 (Japan).Search for more papers by this authorNobuyuki Iwane, Nobuyuki Iwane Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226–8502 (Japan)Search for more papers by this authorYu Harada, Yu Harada Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226–8502 (Japan)Search for more papers by this authorShin-ichi Nishimura, Shin-ichi Nishimura Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Building 5–607, 7–3-1 Hongo, Bunkyo-ku, Tokyo 113–8656 (Japan)Search for more papers by this authorYukinori Koyama, Yukinori Koyama Department of Materials Science and Engineering, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606–8501 (Japan)Search for more papers by this authorIsao Tanaka, Isao Tanaka Department of Materials Science and Engineering, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606–8501 (Japan)Search for more papers by this author Atsuo Yamada, Corresponding Author Atsuo Yamada [email protected] Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Building 5–607, 7–3-1 Hongo, Bunkyo-ku, Tokyo 113–8656 (Japan)Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Building 5–607, 7–3-1 Hongo, Bunkyo-ku, Tokyo 113–8656 (Japan).Search for more papers by this authorNobuyuki Iwane, Nobuyuki Iwane Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226–8502 (Japan)Search for more papers by this authorYu Harada, Yu Harada Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226–8502 (Japan)Search for more papers by this authorShin-ichi Nishimura, Shin-ichi Nishimura Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Building 5–607, 7–3-1 Hongo, Bunkyo-ku, Tokyo 113–8656 (Japan)Search for more papers by this authorYukinori Koyama, Yukinori Koyama Department of Materials Science and Engineering, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606–8501 (Japan)Search for more papers by this authorIsao Tanaka, Isao Tanaka Department of Materials Science and Engineering, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606–8501 (Japan)Search for more papers by this author First published: 09 June 2010 https://doi.org/10.1002/adma.201001039Citations: 211Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Beyond the limited lithium storage capability of the (PO4)3−-based compound, LiFePO4 (170 mAh/g), which is currently recognized as the most promising lithium battery cathode for large-scale application, a compound with the lightest small triangle oxyanion unit (BO3)3−, namely LiFeBO3, exhibits a much larger reversible capacity of ca. 200 mAh/g with surprisingly small volume change of ca. 2%. References 1 M. Armand, J. M. Tarascon, Nature 2008, 451, 652. 2 A. K. Padhi, K. S. Nanjundaswamy, J. B. Goodenough, J. Electrochem. Soc. 1997, 144, 1188. 3 N. Ravet, J. B. Goodenough, S. Besner, M. Simoneau, P. Hovington, M. Armand, Abstract 127, The Electrochemical Society and The Electrochemical Society of Japan Meeting Abstracts, Vol. 99–2, Honolulu, Hawaii, Oct 17–22, 1999. 4 A. Yamada, S. C. Chung, K. Hinokuma, J. Electrochem. Soc. 2001, 148, A224. 5 S. Y. Chung, J. T. Blocking, Y. M. Chiang, Nat. Mater. 2002, 1, 123. 6 B. Kang, G. 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Volume22, Issue32August 24, 2010Pages 3583-3587 ReferencesRelatedInformation