塔菲尔方程
过电位
材料科学
电催化剂
催化作用
密度泛函理论
分解水
纳米材料基催化剂
析氧
化学工程
相(物质)
兴奋剂
化学物理
纳米技术
氢
物理化学
电极
电化学
计算化学
光电子学
化学
纳米颗粒
有机化学
光催化
工程类
作者
Yaqian Wang,Yongli Shen,Xiong Xiao,Linxiu Dai,Shuang Yao,Changhua An
标识
DOI:10.1007/s40843-020-1612-y
摘要
Metastable 1T′ MoTe2 has attracted much attention as a cost-effective electrocatalyst for hydrogen evolution reaction (HER) in recent years. However, few studies were done over common stable 2H phase because it often exhibits inferior performance. Herein, stable 2H MoTe2 with S-doped Te vacancies has been synthesized by one-step telluride conversion of 1T MoS2 at 700°C under Ar/H2 atmosphere. It is demonstrated that the synergistic effect of S-doping and Te vacancies changes the electronic structures of the catalyst. Density functional theory (DFT) studies show that plentiful electrons accumulate on the surface S atoms in S-doped Te vacancies of 2H MoTe2 catalyst, which may be as active sites to promote HER. Moreover, the as-synthesized catalyst can be directly used as working electrode, and realizes current density of 100 mA cm−2 at overpotential of 217 mV with Tafel slope of 94 mV dec−1. This work stimulates intensive studies on the activation of inert phase of other nanocatalysts towards various reactions.
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