金红石
材料科学
锐钛矿
退火(玻璃)
微晶
纳米管
化学工程
纳米晶材料
纳米技术
分解水
光催化
复合材料
冶金
化学
催化作用
碳纳米管
工程类
生物化学
作者
Fumiaki Amano,Hyosuke Mukohara,Ayami Shintani
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2018-01-01
卷期号:165 (4): H3164-H3169
被引量:12
摘要
TiO2 nanotube arrays fabricated by anodization and post annealing are extensively studied as an n-type semiconductor electrode for photoelectrochemical (PEC) water splitting owing to their large surface area and efficient electron transport property. The rutile phase is believed to be an inactive component of the TiO2 nanotube's electrode because annealing at high temperatures decreases the PEC efficiency with the transformation of anatase into rutile crystallites. In contrast, herein, we found that photoelectrodes prepared by two-step annealing, in which TiO2 nanotubes annealed in air at 650°C were then treated in a nitrogen atmosphere at a higher temperature, exhibited higher PEC efficiency despite the anatase nanotube structure changes to rutile particles. Sheet resistance measurement and Mott–Schottky analysis showed that the enhanced efficiency is attributed to a significant increase in donor density by partial reduction of rutile TiO2. The second annealing in the reductive atmosphere is essential to provide a columnar arrangement of TiO2 crystallites with high donor density resulting in high PEC properties for the oxidation of water to O2. This suggests that improving the electron transport property by the enhanced electrical conductivity and the interconnected nanocrystalline structure is important to enhance the PEC property of rutile TiO2 particulate photoanodes.
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